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Install
Most likely you need Pidgin first :) Get it here.
After you have installed it check HowToUse.
Windows
Just execute the installer, which you can find here.
Ubuntu
Use the Ubuntu Software Center and search for msn-pecan, or type in a terminal:
sudo apt-get install msn-pecan
Fedora
Go to Administration->Add/Remove Software, and search for purple-msn-pecan, or type in a terminal:
sudo yum install purple-msn-pecan
Debian
Typing in a terminal:
sudo apt-get install msn-pecan
Arch Linux
You need to compile it from AUR, here is the package.
Nokia N900
Go to the Maemo downloads page.
Gentoo
emerge msn-pecan
Pidgin Portable
You'll be asked for a location, go where Pidgin Portable is installed, and then into plugins subdir.
Adium (Mac OS X)
http://code.google.com/p/msn-pecan/wiki/AdiumBuilds
FreeBSD
cd /usr/ports/net-im/pidgin-msn-pecan && make install clean
Compile
Make sure you have the development files for libpurple (libpurple-devel in RPM based distros, libpurple-dev in Debian ones).
Then, simply download/extract the tarball and issue:
make
sudo make install
And for translations:
sudo make install_locales